宁夏出台新型智慧城市建设实施意见
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????????(II) ??????????
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??????????? ??????????, ???????? ??????????, β-????????(II) ??????????
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21041-93-0 ![]() | |
ChemSpider | 8305419 ![]() |
????? -3D ????????? | Image |
??????? | 10129900 |
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Co(OH)2 | |
???????????? ??? | 92.948 ??/???? |
??????? | ???? ??????? ???? ?????? ????? ????? ???? |
???????? | 3.597 ??/??.??3 |
????????? | 168 °C (334 °F; 441 K) (???????????)[1] |
3.20 ??.??/?? | |
???????? ????????? (Ksp)
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1.0×10-15 |
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Std enthalpy of formation ΔfH |
-539.7 ??????????1 |
???? ?????? ??????????? S |
79.0 ??????????1?K?1[1] |
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?????? ?????????? ???????? ???? | Oxford University |
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R-???????????? | R20 R21 R22 R36 R37 R38 R43 |
S-???????????? | S24 S26 S36 S37 S39[2] |
?????????? ?????????? | |
???? ????? ??????????? | ????????(II) ???????? ????????(II) ???????? ????????(II) ??????? |
???? ???? ??????????? | ???????(II) ?????????? ???????(II) ?????????? ?????(II) ?????????? |
???????? ????? ??????????? ??????? ????????????? ??????? ?????? ????????? ???????? ??????? ????? ?????? ???????? (25°C, 100kPa) ?????????. | |
????????(II) ?????????? (Cobalt(II) hydroxide) ?????? Co(OH)2.???? ??????????? ?????????? ????? ??? ???? ????????? ???????????. ??? ??????????? ?????????? ???? ????????? ??????????????. ???? ??????? ????? ????? ??? ?????????????. α-Co(OH)2, ???? ??????????????? ????? ??? ??? ??????????????????? ???????? ?????????????? [3]. ?????????, ?????, ?????????? ?????????? ??????? ????????(II) ?????????? ????????????????????. ??? ???????? ?????????? ??????????????, ?????? ??????? ??????????? ???????? ??????????????? ??? ????????????????? ????? ????????????????????.
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[????]??? ???? ????????????? ????? Co2+ ??????? ???????? ?????????????? ????????(II) ?????????? ???????? ?????????????? :[4]
- Co2+ + 2 NaOH → Co(OH)2 + 2 Na+.
????????(II) ?????????? 168 ° ????????? ????????????? ????????????? ????????????????? ????????(II) ???????? ????????????. ???????? ??????????????? ????????. 300 ° ????????? ????????????? ???? ??????????????? Co3O4 ?????????? [5][6]. ???????(II) ?????????? ????? ????????(II) ???????????? ??? ???????? ??????????????. ??? ???? ????? ??????????? [Co(H2O)6]2+ ???? ??????? ???????? ??????????. ???????? ?????????? ??????? ?????????? ????????? ??????? ?????? [Co(OH)4]2? ??????? [Co(OH)6]4?????? ???? ??? ????????????(II) ????????? ??????????.
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[????]?????????? ?????? ???????????? ????????(II) ?????????? ???????????. ???????, ????????? ?????????, ???????? ????????? ????????? ????????? ?????? ??? ????????????. ????? ????????? ?????? ??????????? ???????? ?????????? [7]. ?????????? ????????? α-Co(OH)2 ??????? β-Co(OH)2 ???????????? ??????????? ????????? ????????? ??????? ?????. ????? ??? ???????????? ?????????? ????????. ?????????????????? ????????? ??????? ??????????????? ??????????????. ???? ??? ??? ????????? ???????? ????????????. β-Co(OH)2 ????????????? α-Co(OH)2 ??????? ??? ?????????? ??????? ?????? [8]

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[????]- ↑ 1.0 1.1 Lide, David R. (1998). Handbook of Chemistry and Physics (87 ed.). Boca Raton, FL: CRC Press. p. 513. ISBN 0-8493-0594-2.
- ↑ "Safety (MSDS) data for cobalt (II) hydroxide". Oxford University. Archived from the original on 2025-08-05. Retrieved 2025-08-05.
- ↑ Lide, David R. (1998). Handbook of Chemistry and Physics (87 ed.). Boca Raton, FL: CRC Press. p. 454. ISBN 0-8493-0594-2.
- ↑ O. Glemser "Cobalt(II) Hydroxide" in Handbook of Preparative Inorganic Chemistry, 2nd Ed. Edited by G. Brauer, Academic Press, 1963, NY. Vol. 1. p. 1521.
- ↑ Jayashree, R. S.; Kamath, P. Vishnu (1999). "Electrochemical synthesis of a-cobalt hydroxide". Journal of Materials Chemistry 9 (4): 961–963. doi:10.1039/A807000H.
- ↑ Xu, Z. P.; Zeng, H. C. (1998). "Thermal evolution of cobalt hydroxides: a comparative study of their various structural phases". Journal of Materials Chemistry 8 (11): 2499–2506. doi:10.1039/A804767G.
- ↑ Wiberg, Nils; Wiberg, Egon; Holleman, A. F. (2001). Inorganic Chemistry. Academic Press. pp. 1478–1479. ISBN 0-12-352651-5. Retrieved 2025-08-05.
- ↑ Liu, Zhaoping; Ma, Renzhi; Osada, Minoru; Takada, Kazunori; Sasaki, Takayoshi (2005). "Selective and Controlled Synthesis of α- and β-Cobalt Hydroxides in Highly Developed Hexagonal Platelets". Journal of the American Chemical Society 127: 13869–13874. doi:10.1021/ja0523338.
- ↑ Ni, Bing; Liu, Huiling; Wang, Peng-Peng; He, Jie; Wang, Xun (2015). "General synthesis of inorganic single-walled nanotubes". Nature Communications 6: 8756. doi:10.1038/ncomms9756. ???????:26510862.